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Perfumes do not very often produce skin problems but occasionally people find that they are allergic to one particular type of perfume. It is impossible to find out all of the constituents of all the perfumes available (manufacturers are naturally secretive) so if you do develop a rash with a particular type of perfume, try to find another perfume that you like, and that doesn't upset your skin. If you have sensitive skin and find a perfume that suits you, stick with it or at least with that .particular manufacturer.
One last warning: perfumes can cause blotchy sun tanning so, if you're going to sunbathe, it is sensible not to put on any perfume.